The transparency of Cd(0001) films grown on Si(111)-7×7: Imaging the interface at atomic scale

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SCIENTIA SINICA Physica, Mechanica & Astronomica, Volume 47, Issue 6: 066801(2017) https://doi.org/10.1360/SSPMA2016-00374

The transparency of Cd(0001) films grown on Si(111)-7×7: Imaging the interface at atomic scale

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  • ReceivedAug 29, 2016
  • AcceptedSep 30, 2016
  • PublishedJan 24, 2017
PACS numbers

Abstract

The interfacial structure plays a crucial role in controlling the growth of epitaxial film. However, it is still a formidable task to observe the interface structure at the atomic scale, because the detected signals from the interface become very weak due to the strong attenuation and decoherence when the incident wave passes through the films. With the advent of scanning tunneling microscopy (STM), significant progress has been made in observing the interface structure of thin films. Many studies have demonstrated the typical Si(111)-7×7 superstructure below the metal films in the past. Although the 7×7 superstructures are visible, the 12 Si adatoms in the unit cells can not be resolved. Hence, imaging the 7×7 superstructures below thin films at the atomic scale has not been achieved. In this work, we have grown the Cd epitaxial films with high quality on Si(111)-7×7 substrate, and realized the imaging of interface structure of Cd(0001) at atomic scale by using low temperature scanning tunneling microscopy. Under low bias voltage, we can clearly observe the atomic image of Si(111)-7×7, indicating the Si (111)-7×7 substrate remains intact during the growth process of Cd films. Moreover, due to the quantum size effect, the Cd films with even or odd monolayers exhibit distinct lateral resolution as well as surface roughness, even at the same bias voltage. With the bias variation, such kind of diversities can be reversed. We attribute the highly transparency of Cd(0001) films to the anisotropic effective mass of the electrons in Cd films, i.e. the transverse motion is much faster than the in-plane motion.


Funded by

国家自然科学基金资助项目(10974156)


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  • Figure 1

    (Color online) Morphology of the epitaxial Cd films. (a) Cd films at 3.5 monolayers, 500 nm×500 nm, 4.0 V; (b) Cd films at 10.0 monolayers, 500 nm×500 nm, 4.0 V, the red dashed line marks the position of Si step; (c) the cross-sectional line profile along the black line in (b).

  • Figure 2

    (Color online) The transparences of Cd film under different bias voltages. (a) STM image of the Cd film under 1.5 V, 20 nm×20 nm; (b) STM image of the Cd films under 0.1 V, 30 nm×30 nm; (c) STM image of a pristine Si (111)-7×7 surface, 30 nm×30 nm, 1.9 V; (d) a close-up view of (b), 10 nm×10 nm, 0.1 V; (e) and (f) are the Fourier transform of (b) and(c), respectively.

  • Figure 3

    (Color online) Difference of the lateral resolutions for the even and odd monolayers of Cd films. The vertical boundary is a Si step. (a) STM image under 1.0 V. 24 nm×24 nm; (b) STM image under 0.1 V. 24 nm×24 nm; (c) the dI/dV spectrums measured at the 6 and 7 monolayers (ML) Cd, respectively, two green lines represent the positions of 0.1 and 1.0 V, respectively.

  • Figure 4

    Difference in the surface roughness of the even and odd monolayers of Cd. (a) STM image of a Cd island crossing a Si step at high bias, 130 nm×130 nm, 4.0 V. The diagonal boundary represents a Si step, the Cd island is divided into two regions by the diagonal boundary, labeled as A and B with the thickness of 7 and 8 monolayers, respectively; (b) STM image of the same Cd island at the bias of 2.2 V, 130 nm×130 nm.

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