The interfacial structure plays a crucial role in controlling the
growth of epitaxial film. However, it is still a formidable task to
observe the interface structure at the atomic scale, because the detected
signals from the interface become very weak due to the strong attenuation
and decoherence when the incident wave passes through the films. With
the advent of scanning tunneling microscopy (STM), significant progress
has been made in observing the interface structure of thin films.
Many studies have demonstrated the typical Si(111)-7×7 superstructure
below the metal films in the past. Although the 7×7 superstructures
are visible, the 12 Si adatoms in the unit cells can not be resolved.
Hence, imaging the 7×7 superstructures below thin films at the atomic
scale has not been achieved. In this work, we have grown the Cd epitaxial
films with high quality on Si(111)-7×7 substrate, and realized the
imaging of interface structure of Cd(0001) at atomic scale by using
low temperature scanning tunneling microscopy. Under
国家自然科学基金资助项目(10974156)
[1] Altfeder I B, Chen D M, Matveev K A. Imaging buried interfacial lattices with quantized electrons. Phys Rev Lett, 1998, 80: 4895-4898 CrossRef ADS Google Scholar
[2] Yu H B, Jiang C S, Ebert P, et al. Probing the step structure of buried metal/semiconductor interfaces using quantized electron states: The case of Pb on Si(111) 6×6-Au. Appl Phys Lett, 2002, 81: 2005-2007 CrossRef ADS Google Scholar
[3] Ederer D L, Carlisle J A, Jimenez J, et al. Study of buried interfaces by soft X-ray fluorescence spectroscopy excited by synchrotron radiation. J Vac Sci Tech A, 1996, 14: 859-866 CrossRef Google Scholar
[4] Tromp R M, Denier Van Der Gon A W, Legoues F K, et al. Observation of buried interfaces with low energy electron microscopy. Phys Rev Lett, 1993, 71: 3299-3302 CrossRef PubMed ADS Google Scholar
[5] Meyer T, Von K?nel H. Study of interfacial point defects by ballistic electron emission microscopy. Phys Rev Lett, 1997, 78: 3133-3136 CrossRef ADS Google Scholar
[6] Novet T, McConnell J M, Johnson D C. Low-temperature reaction of buried metal-silicon interfaces: The evolution of interfacial structure. Chem Mater, 1992, 4: 473-478 CrossRef Google Scholar
[7] Heinze S, Abt R, Blügel S, et al. Scanning tunneling microscopy images of transition-metal structures buried below noble-metal surfaces. Phys Rev Lett, 1999, 83: 4808-4811 CrossRef ADS Google Scholar
[8] Didiot C, Vedeneev A, Fagot-Revurat Y, et al. Imaging a buried interface by scanning tunneling spectroscopy of surface states in a metallic system. Phys Rev B, 2005, 72: 233408 CrossRef ADS Google Scholar
[9] Kubby J A, Greene W J. Electron interferometry at a metal-semiconductor interface. Phys Rev Lett, 1992, 68: 329-332 CrossRef PubMed ADS Google Scholar
[10] Yakes M, Tringides M C. Probing the buried Pb/Si(111) interface with SPA LEED and STM on Si(111)-Pb α√3′√3. J Phys Chem A, 2011, 115: 7096-7104 CrossRef PubMed ADS Google Scholar
[11] Jian W B, Su W B, Chang C S, et al. Vertical friedel oscillations in interface-induced surface charge modulations of ultrathin quantum islands. Phys Rev Lett, 2003, 90: 196603 CrossRef PubMed ADS Google Scholar
[12] Altfeder I B, Narayanamurti V, Chen D M. Imaging subsurface reflection phase with quantized electrons. Phys Rev Lett, 2002, 88: 206801 CrossRef PubMed ADS Google Scholar
[13] Schmid M, Hebenstreit W, Varga P, et al. Quantum wells and electron interference phenomena in Al due to subsurface noble gas bubbles. Phys Rev Lett, 1996, 76: 2298-2301 CrossRef PubMed ADS Google Scholar
[14] Altfeder I B, Matveev K A, Chen D M. Electron fringes on a quantum wedge. Phys Rev Lett, 1997, 78: 2815-2818 CrossRef ADS Google Scholar
[15]
Le Fèvre
P,
Magnan
H,
Chandesris
D.
X-ray absorption at the
[16]
Pikma
P,
Grozovski
V,
Kasuk
H, et al.
[17] Altfeder I B, Liang X, Yamada T, et al. Anisotropic metal-insulator transition in epitaxial thin films. Phys Rev Lett, 2004, 92: 226404 CrossRef PubMed ADS Google Scholar
[18] Schmid M, Crampin S, Varga P. STM and STS of bulk electron scattering by subsurface objects. J Electron Spectrosc Relat Phenom, 2000, 109: 71-84 CrossRef Google Scholar
[19] Stark R W, Falicov L M. Band structure and fermi surface of zinc and cadmium. Phys Rev Lett, 1967, 19: 795-798 CrossRef ADS Google Scholar
[20] Chauhan H S, Ilver L, Nilsson P O, et al. Direct- and inverse-photoemission investigations of the electronic structure of Cd(0001). Phys Rev B, 1993, 48: 4729-4734 CrossRef ADS Google Scholar
Figure 1
(Color online) Morphology of the epitaxial Cd films. (a) Cd films at 3.5 monolayers, 500 nm×500 nm, 4.0 V; (b) Cd films at 10.0 monolayers, 500 nm×500 nm, 4.0 V, the red dashed line marks the position of Si step; (c) the cross-sectional line profile along the black line in (b).
Figure 2
(Color online) The transparences of Cd film under different bias voltages. (a) STM image of the Cd film under 1.5 V, 20 nm×20 nm; (b) STM image of the Cd films under 0.1 V, 30 nm×30 nm; (c) STM image of a pristine Si (111)-7×7 surface, 30 nm×30 nm, 1.9 V; (d) a close-up view of (b), 10 nm×10 nm, 0.1 V; (e) and (f) are the Fourier transform of (b) and(c), respectively.
Figure 3
(Color online) Difference of the lateral resolutions for the even and odd monolayers of Cd films. The vertical boundary is a Si step. (a) STM image under 1.0 V. 24 nm×24 nm; (b) STM image under 0.1 V. 24 nm×24 nm; (c) the d
Figure 4
Difference in the surface roughness of the even and odd monolayers of Cd. (a) STM image of a Cd island crossing a Si step at high bias,
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